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dc.contributor.authorTaylor, Lauren L K; orcid: 0000-0003-0586-3246
dc.contributor.authorVitorica-Yrezabal, Iñigo J
dc.contributor.authorBorilović, Ivana
dc.contributor.authorTuna, Floriana; orcid: 0000-0002-5541-1750
dc.contributor.authorRiddell, Imogen A; orcid: 0000-0002-6801-0198
dc.date.accessioned2021-10-25T00:39:04Z
dc.date.available2021-10-25T00:39:04Z
dc.date.issued2021-10-11
dc.identifierpubmed: 34632988
dc.identifierdoi: 10.1039/d1cc04413c
dc.identifier.citationChemical communications (Cambridge, England)
dc.identifier.urihttp://hdl.handle.net/10034/626190
dc.descriptionFrom PubMed via Jisc Publications Router
dc.descriptionPublication status: aheadofprint
dc.description.abstractSelf-assembly and characterisation of a supramolecular trigonal bipyramidal iron cage containing an [Fe (μ -F) (Fe ) ] star motif at its core is reported. The complex can be formed in a one step reaction using an heterotopic ligand that supports site-specific incorporation of iron in three distinct electronic configurations: low-spin Fe , high-spin Fe and high-spin Fe , with iron(II) tetrafluoroborate as the source of the bridging fluorides. Formation of a μ -F bridged mixed-valence Fe -Fe star is unprecedented. The peripheral high-spin Fe centres of the mixed-valence tetranuclear star incorporated in the iron cage are highly anisotropic and engage in F-mediated antiferromagnetic exchange with the central Fe ion.
dc.languageeng
dc.sourceeissn: 1364-548X
dc.titleSelf-assembly of a trigonal bipyramidal architecture with stabilisation of iron in three spin states.
dc.typearticle
dc.date.updated2021-10-25T00:39:03Z


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