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dc.contributor.authorLuo, Tian
dc.contributor.authorLi, Lili
dc.contributor.authorChen, Yinlin; orcid: 0000-0001-7878-2063
dc.contributor.authorAn, Jie; email: jie_an@cau.edu.cn
dc.contributor.authorLiu, Chengcheng
dc.contributor.authorYan, Zheng
dc.contributor.authorCarter, Joseph H.; orcid: 0000-0001-5530-7390
dc.contributor.authorHan, Xue
dc.contributor.authorSheveleva, Alena M.
dc.contributor.authorTuna, Floriana; orcid: 0000-0002-5541-1750
dc.contributor.authorMcInnes, Eric J. L.; orcid: 0000-0002-4090-7040
dc.contributor.authorTang, Chiu C.
dc.contributor.authorSchröder, Martin; orcid: 0000-0001-6992-0700; email: m.schroder@manchester.ac.uk
dc.contributor.authorYang, Sihai; orcid: 0000-0002-1111-9272; email: Sihai.Yang@manchester.ac.uk
dc.date.accessioned2021-06-11T17:15:21Z
dc.date.available2021-06-11T17:15:21Z
dc.date.issued2021-06-11
dc.date.submitted2020-08-26
dc.identifierhttps://chesterrep.openrepository.com/bitstream/handle/10034/624914/41467_2021_Article_23302.pdf?sequence=2
dc.identifierhttps://chesterrep.openrepository.com/bitstream/handle/10034/624914/41467_2021_Article_23302_nlm.xml?sequence=3
dc.identifierhttps://chesterrep.openrepository.com/bitstream/handle/10034/624914/41467_2021_23302_MOESM1_ESM.pdf?sequence=4
dc.identifierhttps://chesterrep.openrepository.com/bitstream/handle/10034/624914/41467_2021_23302_MOESM2_ESM.pdf?sequence=5
dc.identifier.citationNature Communications, volume 12, issue 1, page 3583
dc.identifier.urihttp://hdl.handle.net/10034/624914
dc.descriptionFrom Springer Nature via Jisc Publications Router
dc.descriptionHistory: received 2020-08-26, accepted 2021-03-29, registration 2021-04-23, pub-electronic 2021-06-11, online 2021-06-11, collection 2021-12
dc.descriptionPublication status: Published
dc.descriptionFunder: EC | EU Framework Programme for Research and Innovation H2020 | H2020 Priority Excellent Science | H2020 European Research Council (H2020 Excellent Science - European Research Council); doi: https://doi.org/10.13039/100010663; Grant(s): 742401
dc.descriptionFunder: RCUK | Engineering and Physical Sciences Research Council (EPSRC); doi: https://doi.org/10.13039/501100000266; Grant(s): EP/I011870
dc.description.abstractAbstract: Construction of C-C bonds via reductive coupling of aldehydes and ketones is hindered by the highly negative reduction potential of these carbonyl substrates, particularly ketones, and this renders the formation of ketyl radicals extremely endergonic. Here, we report the efficient activation of carbonyl compounds by the formation of specific host-guest interactions in a hydroxyl-decorated porous photocatalyst. MFM-300(Cr) exhibits a band gap of 1.75 eV and shows excellent catalytic activity and stability towards the photoreductive coupling of 30 different aldehydes and ketones to the corresponding 1,2-diols at room temperature. Synchrotron X-ray diffraction and electron paramagnetic resonance spectroscopy confirm the generation of ketyl radicals via confinement within MFM-300(Cr). This protocol removes simultaneously the need for a precious metal-based photocatalyst or for amine-based sacrificial agents for the photochemical synthesis.
dc.languageen
dc.publisherNature Publishing Group UK
dc.rightsLicence for this article: http://creativecommons.org/licenses/by/4.0/
dc.sourceeissn: 2041-1723
dc.subjectArticle
dc.subject/639/638/77/887
dc.subject/639/301/299/890
dc.subject/140/131
dc.subject/145
dc.subject/128
dc.subject/140/146
dc.subjectarticle
dc.titleConstruction of C-C bonds via photoreductive coupling of ketones and aldehydes in the metal-organic-framework MFM-300(Cr)
dc.typearticle
dc.date.updated2021-06-11T17:15:21Z
dc.date.accepted2021-03-29


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