Capsule membranes encapsulated with smart nanogels for facile detection of trace lead(II) ions in water
AuthorsLiu, Wen Ying
Ju, Xiao Jie
Peng, Han Yu
Liu, Yu Qiong
Chu, Liang Yin
AffiliationSichuan University, University of Chester
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AbstractA novel method based on capsule membranes encapsulated with smart nanogels is successfully developed for facilely detecting trace lead(II) (Pb2+) ions, which are hazardous to both human health and the environment because of their toxicity. The capsule membrane system is composed of a semi-permeable calcium alginate membrane and encapsulated poly(N-isopropylacrylamide-co-acryloylamidobenzo-18-crown-6) (PNB) nanogels. The semi-permeable membrane allows Pb2+ ions and water to pass through quickly, but rejects the encapsulated nanogels and polymers totally. As soon as Pb2+ ions appear in the aqueous environment and enter into the capsule, they can be specifically recognized by encapsulated PNB nanogels via forming 18-crown-6/Pb2+ complexes that cause a Pb2+-induced phase transition of PNB nanogels from hydrophobic to hydrophilic state. As a result, the osmotic pressure inside the capsule membrane increases remarkably, and thus the elastic capsule membrane isothermally swells upon the presence of Pb2+ ions in the environmental aqueous solution. The Pb2+-induced swelling degree of the capsule membrane is dependent on the concentration of Pb2+ ions ([Pb2+]) in water. Thus, the [Pb2+] value in water is able to be easily detected by directly measuring the Pb2+-induced isothermal swelling ratio of the capsule membrane, which we demonstrate by using 15 prepared capsule membranes arranged in a line. The Pb2+-induced swelling ratios of the capsule membrane groups are easily observed with the naked eye, and the detection limit of the [Pb2+] in water is 10-9 mol L-1. Such a proposed method provides an easy and efficient strategy for facile detection of trace threat analytes in water.
CitationLiu W.Y., Ju X.J., Faraj Y., He F., Peng H.Y., Liu Y.Q., Liu Z., Wang W., Xie R., Chu L.Y. (2020). Capsule membranes encapsulated with smart nanogels for facile detection of trace lead(II) ions in water. Journal of Membrane Science, 613, 118523.
JournalJournal of Membrane Science
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