Terahertz Probing Irreversible Phase Transitions Related to Polar Clusters in Bi0.5Na0.5TiO3-based Ferroelectric
Authors
Yang, BinAffiliation
University of ChesterPublication Date
2020-02-16
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Electric-field-induced phase transitions in Bi0.5Na0.5TiO3 (BNT)-based relaxor ferroelectrics are essential to the controlling of their electrical properties and consequently in revolutionizing their dielectric and piezoelectric applications. However, the fundamental understanding of these transitions is a long-standing challenge due to their complex crystal structures. Given the structural inhomogeneity at the nanoscale or sub-nanoscale in these materials, dielectric response characterization based on terahertz (THz) electromagnetic-probe beam-fields, is intrinsically coordinated to lattice dynamics during DC-biased poling cycles. The complex permittivity reveals the field-induced phase transitions to be irreversible. This profoundly counters the claim of reversibility, the conventional support for which, is based upon the peak that is manifest in each of four quadrants of the current-field curves. The mechanism of this irreversibility is solely attributed to polar clusters in the transformed lattices. These represent an extrinsic factor which is quiescent in the THz spectral domain.Citation
Wu, J., Sun, W., Meng, N., Zhang, N., Koval, V. Zhang, V., Donnan, R., Yang, B., Zhang D. & Yan, H. (2020). Terahertz Probing Irreversible Phase Transitions Related to Polar Clusters in Bi0.5Na0.5TiO3-based Ferroelectric. Advanced Electronic Materials, 6(4), 1901373.Publisher
Wiley Open AccessJournal
Advanced Electronic MaterialsType
Articleae974a485f413a2113503eed53cd6c53
10.1002/aelm.201901373
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