Avoiding ambient air and light induced degradation in high-efficiency polymer solar cells by the use of hydrogen-doped zinc oxide as electron extraction material
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Authors
Polydorou, ErmioniSakelis, Elias
Soultati, Anastasia
Kaltzoglou, Andreas
Papadopoulos, Theodoros A.
Briscoe, Joe
Tsikritzis, Dimitris
Fakis, Mihalis
Palilis, Leonidas C.
Kennou, Stella
Argitis, Panagiotis
Falaras, Polycarpos
Davazoglou, Dimitris
Vasilopoulou, Maria
Affiliation
National Center for Scientific Research Demokritos; University of Patras; University of Athens; National Technical University of Athens; University of Chester; Queen Mary University of LondonPublication Date
2017-02-24
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Polymer solar cells have undergone rapid development in recent years. Their limited stability to environmental influence and during illumination, however, still remains a major stumbling block to the commercial application of this technology. Several attempts have been made to address the instability issue, mostly concentrated on the insertion of charge transport interlayers in the device stack. Although zinc oxide (ZnO) is one of the most common electron transport materials in those cells, the presence of defects at the surface and grain boundaries significantly affects the efficiency and stability of the working devices. To address these issues, we herein employ hydrogen-doping of ZnO electron extraction material. It is found that devices based on photoactive layers composed of blends of poly(3-hexylthiophene) (P3HT) with electron acceptors possessing different energy levels, such as [6,6]-phenyl-C70butyric acid methyl ester (PC70BM) or indene-C60 bisadduct (IC60BA) essentially enhanced their photovoltaic performance when using the hydrogen-doped ZnO with maximum power conversion efficiency (PCE) reaching values of 4.62% and 6.65%, respectively, which are much higher than those of the cells with the pristine ZnO (3.08% and 4.51%). Most significantly, the degradation of non-encapsulated solar cells when exposed to ambient or under prolonged illumination is studied and it is found that devices based on un-doped ZnO showed poor environmental stability and significant photo-degradation while those using hydrogen-doped ZnO interlayers exhibited high long-term ambient stability and maintained nearly 80–90% of their initial PCE values after 40 h of 1.5 AM illumination. All mechanisms responsible for this enhanced stability are elucidated and corresponding models are proposed. This work successfully addresses and tackles the instability problem of polymer solar cells and the key findings pave the way for the upscaling of these and, perhaps, of related devices such as perovskite solar cells.Citation
Polydorou, E., et. al. (2017). Avoiding ambient air and light induced degradation in high-efficiency polymer solar cells by the use of hydrogen-doped zinc oxide as electron extraction material. Nanoenergy, 34, 500. DOI: 10.1016/j.nanoen.2017.02.047Publisher
ElsevierJournal
Nano EnergyAdditional Links
http://www.sciencedirect.com/science/article/pii/S2211285517301258Type
ArticleLanguage
enISSN
2211-2855ae974a485f413a2113503eed53cd6c53
10.1016/j.nanoen.2017.02.047
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Except where otherwise noted, this item's license is described as http://creativecommons.org/licenses/by-nc-nd/4.0/