Mononuclear Transition Metal Complexes of 7-Nitro-1,3,5-Triazaadamantane

Hdl Handle:
http://hdl.handle.net/10034/612759
Title:
Mononuclear Transition Metal Complexes of 7-Nitro-1,3,5-Triazaadamantane
Authors:
Wagner, Gabriele; Horton, Peter N.; Coles, Simon J.
Abstract:
Complexes of the type [MCl2(7-nitro-1,3,5-triaza-adamantane)2] (M = Zn(II), Pd(II), Pt(II)) and [MCl2(H2O)2(7-nitro-1,3,5-triazaadamantane) 2] (M = Mn (II), Co(II), Ni(II)) have been prepared and their structures have been analysed by X-ray crystallography, elemental analysis, IR and solid state 13C and 15N NMR spectroscopy, supported by density functional theory/ gauge independent atomic orbital (DFT/GIAO) calculations. In each case, 7-nitro-1,3,5-triazaadamantane acts as a mono-dentate ligand and binds to one metal centre only, in spite of the presence of three equivalent amino nitrogens. In the Co(II) and Ni(II) complexes, a two-dimensional intermolecular hydrogen bonding network between the aqua- and the chloro ligands is established. The uncoordinated amines of the 7-nitro-1,3,5-triaza- adamantane are not involved in any H-bonding, as a result of the exceptionally low basicity of this compound.
Affiliation:
University of Chester; University of Southampton
Citation:
Wagner, G., Horton, P. N., & Coles, S. J. (2016). Mononuclear Transition Metal Complexes of 7-Nitro-1,3,5-Triazaadamantane. ChemistrySelect, 1(8), 1548-1555. DOI: 10.1002/slct.201600502
Publisher:
Wiley-Blackwell
Journal:
ChemistrySelect
Publication Date:
6-Jun-2016
URI:
http://hdl.handle.net/10034/612759
DOI:
10.1002/slct.201600502
Additional Links:
http://onlinelibrary.wiley.com/doi/10.1002/slct.201600502/abstract
Type:
Article
Language:
en
Description:
This is the peer reviewed version of the following article: Wagner, G., Horton, P. N., & Coles, S. J. (2016). Mononuclear Transition Metal Complexes of 7-Nitro-1,3,5-Triazaadamantane. ChemistrySelect, 1(8), 1548-1555. DOI: 10.1002/slct.201600502, which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1002/slct.201600502/abstract. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving
ISSN:
2365-6549
Appears in Collections:
Natural Sciences

Full metadata record

DC FieldValue Language
dc.contributor.authorWagner, Gabrieleen
dc.contributor.authorHorton, Peter N.en
dc.contributor.authorColes, Simon J.en
dc.date.accessioned2016-06-13T13:34:46Zen
dc.date.available2016-06-13T13:34:46Zen
dc.date.issued2016-06-06en
dc.identifier.citationWagner, G., Horton, P. N., & Coles, S. J. (2016). Mononuclear Transition Metal Complexes of 7-Nitro-1,3,5-Triazaadamantane. ChemistrySelect, 1(8), 1548-1555. DOI: 10.1002/slct.201600502en
dc.identifier.issn2365-6549en
dc.identifier.doi10.1002/slct.201600502en
dc.identifier.urihttp://hdl.handle.net/10034/612759en
dc.descriptionThis is the peer reviewed version of the following article: Wagner, G., Horton, P. N., & Coles, S. J. (2016). Mononuclear Transition Metal Complexes of 7-Nitro-1,3,5-Triazaadamantane. ChemistrySelect, 1(8), 1548-1555. DOI: 10.1002/slct.201600502, which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1002/slct.201600502/abstract. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archivingen
dc.description.abstractComplexes of the type [MCl2(7-nitro-1,3,5-triaza-adamantane)2] (M = Zn(II), Pd(II), Pt(II)) and [MCl2(H2O)2(7-nitro-1,3,5-triazaadamantane) 2] (M = Mn (II), Co(II), Ni(II)) have been prepared and their structures have been analysed by X-ray crystallography, elemental analysis, IR and solid state 13C and 15N NMR spectroscopy, supported by density functional theory/ gauge independent atomic orbital (DFT/GIAO) calculations. In each case, 7-nitro-1,3,5-triazaadamantane acts as a mono-dentate ligand and binds to one metal centre only, in spite of the presence of three equivalent amino nitrogens. In the Co(II) and Ni(II) complexes, a two-dimensional intermolecular hydrogen bonding network between the aqua- and the chloro ligands is established. The uncoordinated amines of the 7-nitro-1,3,5-triaza- adamantane are not involved in any H-bonding, as a result of the exceptionally low basicity of this compound.en
dc.language.isoenen
dc.publisherWiley-Blackwellen
dc.relation.urlhttp://onlinelibrary.wiley.com/doi/10.1002/slct.201600502/abstracten
dc.subjectTransition metalsen
dc.subjectCoordination modesen
dc.subjectSolid state NMRen
dc.subjectHydrogen bonding networken
dc.titleMononuclear Transition Metal Complexes of 7-Nitro-1,3,5-Triazaadamantaneen
dc.typeArticleen
dc.contributor.departmentUniversity of Chester; University of Southamptonen
dc.identifier.journalChemistrySelecten
dc.date.accepted2016-05-11en
or.grant.openaccessYesen
rioxxterms.funderUnfundeden
rioxxterms.identifier.projectUnfundeden
rioxxterms.versionAMen
rioxxterms.licenseref.startdate2016-06-06en
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