Synthesis and Characterisation of a New Anion Exchangeable Layered Hydroxyiodide

Hdl Handle:
http://hdl.handle.net/10034/600774
Title:
Synthesis and Characterisation of a New Anion Exchangeable Layered Hydroxyiodide
Authors:
Southworth, Faye Y.; Wilson, Claire; Coles, Simon J.; Fogg, Andrew M.
Abstract:
Lu4O(OH)9I·3H2O is a new member of the anion exchangeable lanthanide hydroxyanion family of materials which has been synthesised hydrothermally. Its structure comprises positively charged [Lu4O(OH)9(H2O)3]+ layers with exchangeable charge balancing iodide anions located in the interlayer gallery. It has been found to undergo facile anion exchange reactions with dicarboxylate anions such as succinate and terephthalate at room temperature but reacts less readily with disulfonate anions such as 1,5- and 2,6-naphthalenedisulfonate under the same conditions. At reaction temperatures above 200 °C the cationic inorganic framework Lu3O(OH)6I·2H2O forms instead of the layered phase.
Affiliation:
University of Liverpool; University of Southampton
Citation:
Southworth, F. Y., Wilson, C., Coles, S. J., Fogg, A. M. (2014). Synthesis and Characterisation of a New Anion Exchangeable Layered Hydroxyiodide. Dalton Transactions, 43(27), 10451-10455. DOI: 10.1039/c4dt00123k
Publisher:
Royal Society of Chemistry
Journal:
Dalton Transactions
Publication Date:
4-Mar-2014
URI:
http://hdl.handle.net/10034/600774
DOI:
10.1039/c4dt00123k
Additional Links:
http://www.ncbi.nlm.nih.gov/pubmed/24590319
Type:
Article
Language:
en
EISSN:
1477-9234
Appears in Collections:
Natural Sciences

Full metadata record

DC FieldValue Language
dc.contributor.authorSouthworth, Faye Y.en
dc.contributor.authorWilson, Claireen
dc.contributor.authorColes, Simon J.en
dc.contributor.authorFogg, Andrew M.en
dc.date.accessioned2016-03-07T16:31:01Zen
dc.date.available2016-03-07T16:31:01Zen
dc.date.issued2014-03-04en
dc.identifier.citationSouthworth, F. Y., Wilson, C., Coles, S. J., Fogg, A. M. (2014). Synthesis and Characterisation of a New Anion Exchangeable Layered Hydroxyiodide. Dalton Transactions, 43(27), 10451-10455. DOI: 10.1039/c4dt00123ken
dc.identifier.doi10.1039/c4dt00123ken
dc.identifier.urihttp://hdl.handle.net/10034/600774en
dc.description.abstractLu4O(OH)9I·3H2O is a new member of the anion exchangeable lanthanide hydroxyanion family of materials which has been synthesised hydrothermally. Its structure comprises positively charged [Lu4O(OH)9(H2O)3]+ layers with exchangeable charge balancing iodide anions located in the interlayer gallery. It has been found to undergo facile anion exchange reactions with dicarboxylate anions such as succinate and terephthalate at room temperature but reacts less readily with disulfonate anions such as 1,5- and 2,6-naphthalenedisulfonate under the same conditions. At reaction temperatures above 200 °C the cationic inorganic framework Lu3O(OH)6I·2H2O forms instead of the layered phase.en
dc.language.isoenen
dc.publisherRoyal Society of Chemistryen
dc.relation.urlhttp://www.ncbi.nlm.nih.gov/pubmed/24590319en
dc.subjectIntercalationen
dc.subjectLanthanideen
dc.titleSynthesis and Characterisation of a New Anion Exchangeable Layered Hydroxyiodideen
dc.typeArticleen
dc.identifier.eissn1477-9234en
dc.contributor.departmentUniversity of Liverpool; University of Southamptonen
dc.identifier.journalDalton Transactionsen
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